Frequently Asked Questions about Electrolysis

What is Faraday's First Law of Electrolysis?

Faraday's First Law states that the mass (m) of a substance deposited or liberated at an electrode is directly proportional to the quantity of electricity (Q) passed through the electrolyte. The formula is m = Z · Q, where Z is the electrochemical equivalent.

How do I calculate theoretical yield in electrolysis?

To calculate the theoretical yield (mass), use the formula: m = (M · I · t) / (n · F).
Where:

  • M = Molar mass of the substance (g/mol)
  • I = Current in Amperes (A)
  • t = Time in seconds (s)
  • n = Valency (number of electrons transferred per ion)
  • F = Faraday's Constant (~96,485 C/mol)

What is current efficiency?

Current efficiency represents the percentage of current that actually goes towards the desired reaction rather than side reactions (like water electrolysis). In real-world scenarios, efficiency is rarely 100%. Our calculator allows you to adjust this factor to see realistic yields.

Can I calculate gas volume with this tool?

Yes! If the product of electrolysis is a gas (like Hydrogen, Oxygen, or Chlorine), this calculator uses the Ideal Gas Law (PV = nRT) to estimate the volume produced based on your specified temperature and pressure conditions.